2 cups all-purpose flour
1 teaspoon baking powder
¼ teaspoon baking soda
¼ teaspoon salt
1 cup (2 sticks) unsalted butter
1 cup boiling water
4 ounces unsweetened chocolate, chopped
2 cups sugar
½ cup buttermilk
2 large eggs
1 tablespoon pure vanilla extract
For the fudge-pecan icing
3 ounces unsweetened chocolate, coarsely chopped
½ cup (1 stick) unsalted butter
1/3 cup buttermilk
1 teaspoon pure vanilla extract
Pinch of salt
3 to 4 cups confectioners’ sugar, sifted
1. Position a rack in the middle of the oven and preheat to 400˚F. Brush a 9 x 13-inch baking pan with melted butter or spray with a nonstick cooking spray.
2. Sift the flour, baking powder, baking soda, and salt together into a large bowl and set aside.
3. Combine the butter, boiling water, and chocolate in a saucepan. Place the saucepan over medium-low heat, and whisk gently until the butter and chocolate are melted and the mixture is smooth. Remove the pan from the heat and whisk in the sugar. Quickly whisk in the buttermilk and then the eggs and vanilla. Using an electric mixer set at medium speed, beat the chocolate mixture into the dry ingredients just until combined and a smooth batter forms, about 1 minute.
4. Pour the batter immediately into the prepared pan. Bake until the cake starts to pull away from the sides of the pan and a wooden skewer inserted into the middle of the cake comes out clean, 20 to 25 minutes.
5. Meanwhile, make the icing: combine the chocolate, butter, buttermilk in a saucepan and cook, stirring over medium heat, until the chocolate is melted. Remove from the heat and whisk in the vanilla, salt and 3 cups of the sifted confectioners sugar. If you would like the icing sweeter and thicker, whisk in the remaining confectioners sugar to taste.
6. Transfer the cake to a wire rack and pour the warm icing over the cake while it, too, is still warm in the pan. Let cool completely, then cut into squares and serve.
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